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The electron diffraction pattern of the vapor from a sample of SeCl4 has been recorded with a reservoir and nozzle temperature of about 175 °C. The gas jet was found to consist of SeCl2 (80%) and Cl2 (20%). The bond distance in SeCl2 is ra(Se-Cl) = 2.157(3) Å, the valence angle
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Fernholt et al. (1983) studied this question.
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