Pattern Formation in Thin Polymer Films Containing Conducting Polyaniline

Summary: In the present work knowledge the authors tried to direct the phase separation process in a thin polymer composite film to manufacture a polymer pattern via self organisation of the blend components. The Au substrate was modified by applying with a PDMS stamp a pattern of alternating stripes of a self‐assembled monolayer. This in turn influenced the microstructure of the blend, allowing for the production of elongated domains repeating the pattern of the substrate. The blends studied in this work contained conducting polyaniline doped with camphorsulfonic acid or diphenyl phosphate and polystyrene. The role of the dopant was to induce electrical conductivity in polyaniline as well as to improve its solubility in common organic solvents. The microstructure of thin films was analysed using atomic force microscopy (AFM), dynamic secondary ion mass spectroscopy (dSIMS) and optical microscopy.