Anomalous Shift in the Fluorescence Spectra of a High‐Generation Dendrimer in Nonpolar Solvents

This is the authors' abstract. We don't add key points for this paper.

The size and shape of the molecules of the aliphatic hydrocarbon solvent have a strong influence on the magnitude of the anomalous spectral shift in the fluorescence maximum of the charge transfer (CT) state of a high-generation dendrimer (shown schematically on the right). Its molecules no longer exist in an open extended form but exhibit a compact, globular structure, and the dipole moment of the CT state in pentane is larger than in cyclohexane.