Lightly crosslinked liquid crystalline epoxy resins: The effect of rigid‐rod length and applied stress on the state of order of the cured thermoset

Lightly crosslinked liquid crystalline epoxy resins were synthesized by reacting rigid rod epoxy‐terminated molecules with decanedioic acid (SA). The obtained networks exhibited a smectic phase even in the case of 2,6‐bis(2,3‐epoxypropoxy)naphthalene, whose aspect ratio is very low. Upon application of uniaxial stress, a smectic phase was surprisingly obtained also for the system obtained by reacting p‐bis(2,3‐epoxypropoxy)‐benzene (QH), whose aspect ratio is practically equal to one, and SA. Stretching of the smectic samples above the glass transition temperature determines orientation of polymer chains, yielding considerably high values of the order parameter S. Thermomechanical analysis showed, for one of these systems, that stretching induces a shift of the isotropization temperature to higher values.