EPR spectra of diatomic halogen centers in alkali halides are investigated. Centers of the type FBr−, FJ−, and CIJ− are identified. The constants of the spin Hamiltonian are derived from the FBr‐ spectra by a perturbation calculation up to fourth order. By studying the photochemical properties of centers of the type X and XY− information regarding the formation mechanismus of the FCl− and FBr− centers are obtained.
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Dreybrodt et al. (1966) studied this question.