Revised model: Current oscillations in the electrooxidation of formic acid at a fixed potential can be observed by time-resolved surface-enhanced infrared absorption spectroscopy (see picture). Real-time probing of the reaction dynamics on the electrode surface provides new insight into the oscillations that are not accessible by conventional techniques. The reaction mechanism involves adsorbed formate as a reactive intermediate.
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Gabor Samjeské (2005) studied this question.
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