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Blossoming promises fruit! A new class of shelf stable organoboron reagents has been obtained from ortho- and laterally lithiated aziridines and benzylamines. Their usefulness as Suzuki–Miyaura reagents has been investigated, proving that they could be fruitful reagents for the preparation of arylated aziridines and benzylamines, even in enantioenriched form, and promising new bifunctional Lewis pairs for catalysis or small-molecule binding.
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Luisi et al. (2010) studied this question.
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