A short synthesis of the alkaloid schumanniophytine (1) starting from simple building blocks and involving directed ortho metalation (DoM), Suzuki–Miyaura cross coupling, and a key ortho‐silicon‐induced O‐carbamate remote anionic Fries rearrangement (3) is described. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
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Macklin et al. (2008) studied this question.
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