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The phase-alternated experiment in liquids, a multiple-pulse NMR experiment capable of scaling chemical shifts, is examined theoretically and experimentally. The theory of the experiment is worked out using both the average-Hamiltonian and classical magnetic-dipole techniques, and the results from the two methods are compared. The effects of nonideal pulse cycles are discussed. Theoretical results are compared with experimental data, and a high-resolution NMR spectrum with scaled chemical shifts is presented.
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Ellett et al. (1969) studied this question.
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