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January 1, 2017Chemical Communications

Synthesis of rare-earth-metal-in-cryptand dications, [Ln(2.2.2-cryptand)] 2+ , from Sm 2+ , Eu 2+ , and Yb 2+ silyl metallocenes (C 5 H 4 SiMe 3 ) 2 Ln(THF) 2

Daniel N. Huh Christopher M. Kotyk Milan Gembický Arnold L. Rheingold Joseph W. Ziller William J. Evans

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Abstract

Ln 2+ -in-cryptand complexes (Ln = Sm, Eu, Yb) containing +2 ions surrounded only by neutral ligands are readily formed from silyl metallocenes.

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Cite This Study

Huh et al. (2017) studied this question.

synapsesocial.com/papers/6a9fbdc426b4e28929efd1c0 https://doi.org/10.1039/c7cc04396a

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