The solubility of ethylbenzene, m -xylene, and benzene in water was determined using a laboratory-made system at temperatures ranging from 298 K to 473 K and a pressure of 50 bars. The solubility was enhanced by at least 1 order of magnitude by increasing the temperature from ambient to 473 K. A simple approximation model was developed to predict the solubility of liquid organics in high-temperature water. This model delivers an excellent estimation of the solubility of small molecules of liquid organic compounds in water at temperatures at or higher than 373 K.
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Mathis et al. (2004) studied this question.
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