A new and versatile method to produce grafted layers of poly(γ-methyl L-glutamate) (PMLG) on silicon wafers by the ring-opening polymerization of γ-methyl L-glutamate N-carboxyanhydride (MLG-NCA) is described. Compared with the polymerizations in solution, this approach provides grafted synthetic polypeptide layers very easily and reproducibly.
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Wieringa et al. (1996) studied this question.
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