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September 8, 2026EnergiesOpen Access

Microwave- Versus Conventional Acid-Assisted Thermohydrolysis of Willow and Maize Silage: Methane Yield and the Energy Cost of Pretreatment

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Authors

ANAnna NowickaMDMagda DudekMZMarcin Zieliński

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Overview

Comparative study reveals net-negative energy balances across acid-assisted thermohydrolysis methods in willow and maize silage, indicating hydrothermal pretreatment fails to recover input energy.

Key Points

  • To determine whether microwave or conventional conductive acid-assisted thermohydrolysis yields a net-positive energy balance while increasing methane production in lignocellulosic biomass.
  • Treated willow (Salix viminalis) and maize silage with acid-assisted thermohydrolysis at temperatures between 110 °C and 130 °C using either microwave or conventional conductive heating.
  • Conducted biochemical methane potential tests (BMP, n = 3) alongside incremental energy balance calculations relative to untreated control substrates.
  • Heating mode, substrate, and temperature all significantly influenced digestion (p < 0.001); microwave heating increased methane yield up to 306.0 ± 4.0 NmL CH4 g−1 VS (+31.4%) in maize silage and 310.6 ± 2.5 NmL CH4 g−1 VS (+28.9%) in willow.
  • Every pretreatment condition produced a net-negative energy return, with the least unfavorable outcomes occurring under microwave heating at 110 °C (-3.57 and -3.48 kJ g−1 DM).
  • Microwave heating reduced the net energy penalty three- to fivefold compared to conductive heating across all six paired comparisons, while furanic by-products remained at non-inhibitory trace levels.

Cite This Study

Nowicka et al. (2026) studied this question.

synapsesocial.com/papers/6a9fd72a58e84d0ff5b459b6https://doi.org/10.3390/en19174230
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