New Freeze‐Casting Technique for Ceramics with Sublimable Vehicles

A new ceramic freeze‐casting technique capable of manufacturing near room temperature with a sublimable vehicle was accomplished. Fluid‐concentrated slurries of Al 2 O 3 powder in molten camphene (C 10 H 16 ) were prepared at 55°C. These slurries were quickly solidified (frozen) at room temperature to yield rigid solid green bodies, followed by frozen camphene removal by sublimation (freeze‐drying) with negligible shrinkage. Sintering without any special binder burnout process yielded sintered bodies with over 98% theoretical density. The proposed advantages include (1) elimination of extremely cold temperatures, (2) elimination of troublesome binder burnout process, and (3) fast manufacturing cycle due to quick solidification.