Answers are grounded in this paper and cite their sources.
All articles of this category Synthesis of Segment C of tautomycin was accomplished from 2 D -sugar derivatives. New heteroconjugate addition strategy allowed stereocontrolled syntheses of the 2 sub-segments, C-1 and C-2, and 3 other diastereoisomers of the latter. Sub-segments were coupled between sulfone carbanion and epoxide electrophile to furnish the spiro ring moiety of the target compound. tautomycin - segment C - heteroconjugate addition - pseudoenantiomer - enantiomer - sulfone
No takes yet. Share an insight, caveat, or question.
Jiang et al. (1995) studied this question.
Synapse has enriched 10 related papers. Consider them for comparative context: