CO2/CH4 Separation by Adsorption using Nanoporous Metal organic Framework Copper‐Benzene‐1,3,5‐tricarboxylate Tablet

Equilibrium data for carbon dioxide and methane adsorption on nanoporous metal organic framework Cu‐BTC powder and tablets were measured in a magnetic suspension balance in the temperature range of 308–373 K and a pressure range of 0–7 bar and fitted with Langmuir model. The tablets adsorption loading is 0.63 mol kg–1 for methane and 3.1 mol kg–1 for carbon dioxide at 1 bar and 308 K, while these values are 0.77 and 3.9 mol kg–1 for powder in the same conditions. Isosteric heats of adsorption were 22.8 and 15.0 kJ mol–1 for carbon dioxide and methane, respectively, on both adsorbents, which indicates a strong adsorption of carbon dioxide. Also, single and binary breakthrough curves were measured in the same temperature range and atmospheric pressure by using Cu‐BTC tablets as adsorbent. A complete model was used in the simulation of breakthrough curves and good agreement was observed with experimental data.