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Cluster catalysts for directed oxygen transfer? In attempts towards the creation of novel catalytic systems for directed oxygen-transfer processes a novel type of polyoxometalate cluster containing vanadium was synthesized. The first example of a polyoxovanadate composed of a hexavanadate molecular center and two reactive, exchangeable, vanadium-centered complexes which are tilted towards the polyoxometalate center is presented (see picture).
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Piepenbrink et al. (2002) studied this question.
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