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November 25, 2003Angewandte Chemie

Heterometallic Cluster Assembly on a Rhenium–Monocarborane Substrate

Shaowu Du J.A. Kautz T.D. McGrath F. G. A. Stone

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Abstract

Ein {ReIrAu2}-Schmetterlingscluster mit Carboransubstituent (siehe Bild; BH grün, B orange, CPh schwarz) wird durch stufenweise Addition von Iridium- und Goldkomplexfragmenten an ein Rhenium-Monocarboran aufgebaut. Diese Strategie könnte sich auch bei der Synthese weiterer neuer Heterometallcluster als nützlich erweisen.

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Du et al. (2003) studied this question.

synapsesocial.com/papers/6aa014b840bc1a697f1df3c2 https://doi.org/10.1002/ange.200352310

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