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O,O-Dimethylkorupensamine A was stereoselectively synthesized by using the palladium(0)-mediated cross-coupling of the enantiomerically pure tricarbonylchromium complex of 3,5-dimethoxy-2-bromobenzene having a functional group at C-1 position with naphthylboronic acid as a key step.
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Watanabe et al. (1998) studied this question.
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