By the employment of supramolecule templates composed of biomembrane and organic reagents, control over the morphologies and sizes of BaWO 4 crystals has been successfully achieved, and a series of flower-like, sphere-like, fasciculus-like, and other morphologies of BaWO 4 were obtained at room temperature. Most of the morphologies are reported for the first time. Furthermore, the control rule of supramolecule templates was also discussed. This method may satisfy the requirements of materials of various morphologies and sizes by using different supramolecule templates, and provide significant theoretical reference to the controlled synthesis of other crystals.
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Liu et al. (2004) studied this question.
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