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Cyanide clusters [Re12CS17(CN)6]n− (n=8 or 6), which may be used to form polymeric material, have been prepared by treating ReS2 with molten KCN at 750 °C. The cluster unit comprises two {Re6} octahedra connected by three μ2-S bridges and one interstitial μ6-C atom (see picture).
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Mironov et al. (2005) studied this question.
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