A catalytic amount of 4-dimethylaminopyridine showed drastic additive effects on transesterification catalyzed by the μ 4 -oxo-tetranuclear zinc cluster Zn 4 (OCOCF 3 ) 6 O, enhancing the catalytic activity by more than 15-fold. The new catalyst system facilitates transesterification of less reactive sterically demanding esters and alcohols.
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Maegawa et al. (2011) studied this question.
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