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The free radical copolymerization of methacrylamide with styrene and methyl methacrylate has been investigated at 70°C in solvents having different dielectric constants. A strong influence of the solvent on the copolymerization parameters has been observed. Such behaviour is quite similar to that found by the same authors for acrylamide copolymerization and differs completely from that found for N.N‐dialkyl acrylamide. The influence of the solvent properties (polarity, dielectric constant etc.) on the amide‐enol equilibrium is discussed.
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Saini et al. (1971) studied this question.
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