Additional data relating to the mechanism of the emulsion copolymerization of styrene and copolymerization of styrene and acrylonitrile are presented. These results show the influence of varying the emulsifier and of varying the water–monomer ratio upon the relationship between monomer composition and the composition of the initial copolymer molecules formed. The composition of the initial copolymer produced in emulsion is the same as that which would be predicted if polymerization occurred in the oil droplet.
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Fordyce et al. (1948) studied this question.
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