An elementary reaction model for the supercritical water oxidation (SCWO) of methylamine was proposed, based on a combustion mechanism that involved reactions relevant to NH 2 CH 2 O 2 . A comparison of the predicted results of our proposed model with the experimental data revealed that our model could predict the conversion via the SCWO of methylamine and the effects of temperature and oxygen concentrations on the NH 3 selectivity quantitatively well, and also could qualitatively explain the trends of the measured product distribution, especially NH 3 as the exclusive nitrogen-containing product of the SCWO of methylamine. This work clarified that the peroxy radical NH 2 CH 2 O 2, which appears in low-temperature combustion through the reaction of O 2 with CH 2 NH 2, and the relevant elementary reactions and intermediate species had key roles in the SCWO of methylamine.
No takes yet. Share an insight, caveat, or question.
Li et al. (2005) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: