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We present the implementation of a CO(2) laser emitting infrared laser irradiation at 10.6 microm onto the versatile atmospheric pressure ionization platform. Infrared laser desorption electrospray ionization (IR-LDESI) is demonstrated from liquid-state samples at atmospheric pressure with and without ESI postionization. Multiply charged proteins ranging in molecular mass from 8.6 to 17 kDa were detected from liquid-state samples without the addition of matrix.
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Sampson et al. (2009) studied this question.
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