A kinetic study of the redox telomerization of vinyl chloride with carbon tetrachloride was carried out. Transfer constants of PVC to the metallic ion (CFen), initiation rate (ki), and functionnality of the resulting telomers were measured. Instantaneous and cumulated polymerization degrees, (DPn)i and (DPn)cum were determined with the help of a theoretical study. These constants provide a rigorous control of the telomerization of vinyl chloride with RCCl3, (R containing an alcohol or ester group).
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Boutevin et al. (1982) studied this question.
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