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The kinetics of elementary steps in the overall process of photoelectrochemical current generation at an illuminated semiconductor‐electrolyte interface can be investigated using relaxation techniques based on perturbations by pulses of illumination. This article reviews theoretical predictions for the form of transients expected under various experimental conditions, and compares these predictions with experimental results. Photopotential, photocurrent, and photoluminescence transient measurements following such perturbations of the semiconductor/electrolyte interface are described.
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S. Gottesfeld (1987) studied this question.
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