Bimetallic nanoparticles: Au–Ag core–shell heterometallic nanorods and icosahedra can be prepared from Au decahedral seed particles using plasmon-mediated synthetic methods and adjusting the pH value of the solution (see picture). This method allows for the preparation of icosahedral nanostructures with an asymmetric metal distribution.
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Langille et al. (2011) studied this question.
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