Poly{2,3-bis(trifluoromethyl)bicyclo[2.2.1]hepta-2,5-diene} is synthesised as a stereoblock copolymer containing cis-and trans-vinylene blocks via ligand exchange in living stereoselective ring opening metathesis polymerisation initiated by a well defined Schrock type initiator.
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Broeders et al. (1996) studied this question.
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