Transition regions and surface melting in partially crystalline polyethylene: A raman spectroscopic study

Structures of semi crystalline high‐molecular weight polyethylene and their changes with temperature were studied by analysis of Raman spectra. Decomposition of spectra into contributions of an orthorhombic crystalline phase, a meltlike phase, and two kinds of transition regions yields the respective mass fractions. The results of temperature dependent measurements is indicative of a largely reversible surface melting process, the transition regions being located at the crystal surfaces. As‐polymerized samples show a large fraction of the intermediate phase. Annealing leads to a reduction of this phase.