Isothermal P, x data and excess enthalpies ( H E ) were measured for the binary systems 2-methyl-1-butene + methyl tert -butyl ether, 2-methyl-1-pentene + tert -amyl ethyl ether, tert -amyl ethyl ether + ethanol, and tert -amyl methyl ether + tert -amyl ethyl ether at approximately 363 K using a static apparatus and an isothermal flow calorimeter. Temperature dependent parameters were fitted simultaneously to the experimental data. Infinite dilution activity coefficients (γ i ∞ ) were derived from the vapor−liquid equilibrium (VLE) data in the dilute region using a flexible Legendre polynomial.
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Heine et al. (1999) studied this question.
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