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The application of phase-transfer catalytic (PTC) conditions leading to substantial improvements in numerous polymerization reactions is described. Generally, better yields as well as faster and cleaner reactions are achieved compared to reactions under conventional conditions. Owing to their ionic mechanisms, polycondensation reactions are the most often applied among polymerization methods under PTC conditions; thus, a number of examples on gram scale are presented in this review.
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Bogdał et al. (2010) studied this question.
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