By using the high order perturbation formula of EPR zero-field splitting for d8 configuration in trigonal crystal field proposed by us, and using the approximate SCF d orbit of Ni2+, an interpretation for the pressure dependence of zero-field splitting of NiSiF6⋅6H2O, which has been a still imperfectly understood problem, is given. In addition, the state equation dependent on pressure for NiSiF6⋅6H2O is predicted.
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Xiong et al. (1985) studied this question.
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