A ring or a cage containing metal and oxygen atoms is formed in the reaction of RSi(OH)3 with HA1-iBu2, depending on the molar ratio used. The structural parameters of the cage compound 1 are very similar to those of the mineral gismondine. Compound 1 is soluble in organic solvents and may suitable for the synthesis of aluminosilicates, in particular zeolites, because of its good leaving groups. R = (2,6-iPr2C6H3)N(SiMe3).
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Montero et al. (1994) studied this question.
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