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January 15, 2013Angewandte Chemie

Palladium‐Catalyzed Intramolecular ipso‐Friedel–Crafts Alkylation of Phenols and Indoles: Rearomatization‐Assisted Oxidative Addition

Tetsuhiro Nemoto Zengduo Zhao Takuya Yokosaka Yuta Suzuki Riliga Wu Yasumasa Hamada

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Abstract

Inspiroierend: Eine neuartige Synthese von Spirocyclen basierend auf einer Palladium-katalysierten intramolekularen ipso-Friedel-Crafts-Alkylierung von Phenolen (siehe Schema; dba=Dibenzylidenaceton) und Indolen wird beschrieben. Mechanistische Studien belegen, dass die Reaktion über eine präzedenzlose Rearomatisierungs-unterstützte oxidative Addition verläuft.

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Nemoto et al. (2013) studied this question.

synapsesocial.com/papers/6aa31a900a11c61cc0c6a282 https://doi.org/10.1002/ange.201209317

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