Rates for the dihydrogen elimination of methane, ethane, and propane with cationic platinum clusters, Pt(n) (+) (1<or=n<or=21), were measured under binary collision conditions in a Fourier transform ion cyclotron resonance mass spectrometer (FTICR). The reaction rate for a given cluster, Ptn +, follows the trend k(CH4)<k (C2H6)
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Adlhart et al. (2007) studied this question.
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