An X‐ray diffraction analysis of the crystalline complex 2b (MLn TiCl4) shows a chelation of the carbonyl O‐atom and the upper SO2 O‐atom by TiCl4, a slightly pyramidal N‐atom, and a π ‐face‐stereoselective shielding of the C(α)‐Si face by the CH2(3) group. The Ti‐atom is in a pseudo‐octahedral environment.
No takes yet. Share an insight, caveat, or question.
Oppolzer et al. (1989) studied this question.
Synapse has enriched 3 closely related papers on similar clinical questions. Consider them for comparative context: