January 1, 1996Chemical Communications

Linear trinuclear three-centred metal–metal multiple bonds: synthesis and crystal structure of [M 3 (dpa) 4 Cl 2 ][M = Ru II or Rh II , dpa = bis(2-pyridyl)amidoanion]

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Abstract

The synthesis and X-ray crystal structures of the linear trinuclear metal complexes, [MII3(dpa)4Cl2](M = Ru or Rh), with a syn–syn bis(2-pyridyl)amido (dpa) ligand, possessing a short M–M–M three-centred multiple bond [Ru–Ru 2.2537(5)Å; Rh–Rh 2.3920(5)Å] are described.

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Sheu et al. (1996) studied this question.

synapsesocial.com/papers/6aa3a61e8204c40fa9c96cac https://doi.org/10.1039/cc9960000315

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Linear trinuclear three-centred metal–metal multiple bonds: synthesis and crystal structure of [M 3 (dpa) 4 Cl 2 ][M = Ru II or Rh II , dpa = bis(2-pyridyl)amidoanion]

Abstract

Discussion

Cite This Study

Linear trinuclear three-centred metal–metal multiple bonds: synthesis and crystal structure of [M 3 (dpa) 4 Cl 2 ][M = Ru II or Rh II , dpa = bis(2-pyridyl)amidoanion]

Abstract

Discussion

Cite This Study

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