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All in a spin: Thermal-driven cis-to-trans supramolecular isomerization was first discovered in a two-dimensional coordination polymer system of [FeII(2,4-bpt)2]⋅xH2O, the spin-crossover properties of which were dramatically changed from a gradual incomplete type to an abrupt complete type.
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Bao et al. (2011) studied this question.
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