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January 1, 2000Chemical Communications

The N,N′-bis(trimethylsilyl)pentafluorobenzamidinate ligand: enhanced ethene oligomerisation with a neutral V(iii) bis(benzamidinate) alkyl catalyst

Edward A. C. Brussee Auke Meetsma B. Hessen Jan H. Teuben

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Abstract

The pentafluorobenzamidinate ligand [C6F5C(NSiMe3)2]− is reported, together with its bis(benzamidinate) vanadium(III) methyl derivative; the latter is considerably more active in catalytic ethene oligomerisation than its non-fluorinated analogue.

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Brussee et al. (2000) studied this question.

synapsesocial.com/papers/6aa3ce13aaaedccdac749c49 https://doi.org/10.1039/b000397m

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