Nitrogen-doped graphene by ball-milling graphite with melamine for energy conversion and storage

N-doped graphene was prepared by ball milling of graphite with melamine. It was found that ball-milling reduced the size of graphite particles from 30 to 1 μ m and facilitated the exfoliation of the resultant small particles into few-layer N-doped graphene nanosheets under ultrasonication. The as-prepared N-doped graphene nanoplatelets (NGnPs) exhibited a nitrogen content as high as 11.4 at.%, making them attractive as efficient electrode materials in supercapacitors for energy storage and as highly-active metal-free catalysts for oxygen reduction in fuel cells for energy conversion.