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The reaction between {HC(MeCDippN)2}Ga: (Dipp = C6H3Pri2 -2,6) and N3SiMe3 afforded the tetrazole {HC(MeCDippN)2}GaN(SiMe3)NNN(SiMe3) 1 and its amide/azide isomer {HC(MeCDippN)2}Ga(N3)N(SiMe3) 2 2 whose stabilities are due to the unique steric properties of the [HC(MeCDippN)2]− ligand.
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Hardman et al. (2001) studied this question.
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