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Direct evidence for the hydrolysis of DNA oligomers by CeIV has been obtained. Three natural enzymes (bacterial alkaline phosphatase, T 4 polynucleotide kinase, and terminal deoxynucleotidyl transferase) quantitatively transformed the fragments obtained by the scission of the DNA oligomer with [Ce(NH4)2(NO3)6] into the expected forms (see scheme below).
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Sumaoka et al. (1998) studied this question.
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