The isomerization of the branched 2M3BN to the linear 3PN by a DPEphosNi species has been investigated by means of variable-temperature NMR spectroscopy, and activation parameters have been determined. An intermediate in this reaction, which is formed via C−C bond activation, could be trapped by addition of ZnCl 2, and the molecular structure of the corresponding Ni(II) complex has been determined by X-ray crystallography.
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Wilting et al. (2004) studied this question.
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