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The polarized electronic absorption spectra of Rb2MnCl4 single crystals are studied down to 77 K in the 15 000 to 45 000 cm−1 spectral region. The observed spectral features can be satisfactorily explained by invoking the four‐parameter (B, C, Dq, and α) ligand field model which indicates the octahedral site symmetry around the Mn2+ ion. Two higher energy bands are found to be due to double‐exciton transitions.
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Ghosh et al. (1981) studied this question.
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