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A striking difference in the clustering efficiency of Ti+ and TiO+ toward N2 or O2 has been observed in a laser vaporization high pressure mass spectrometric source. Evidence for the magic number n=5 within the sequence TiO+(N2)n is presented. The results are consistent with an octahedral structure for TiO+(N2)5.
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Daly et al. (1994) studied this question.
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