⌘+K

Pulse Explore Communities Researchers Journals

Browser extensionInstagram

Home Communities Explore

March 20, 2004Chemistry Letters

A Cationic Diruthenium Amidinate, [(η5-C5Me5)Ru(μ2-i-PrN=C(Me)Ni-Pr)Ru(η5-C5Me5)]+, as an Efficient Catalyst for the Atom-Transfer Radical Reactions

Yukihiro Motoyama Mitsuru Gondo Satoshi Masuda Yuya Iwashita Hideo Nagashima

View at Publisher

Ask AI

Bookmark

Share

Ask about this paper

Answers are grounded in this paper and cite their sources.

Ask your own question…

Abstract

A cationic diruthenium amidinate, [(η5-C5Me5)Ru(μ2-i-PrN=C(Me)Ni-Pr)Ru(η5-C5Me5)]+, is generated by treatment of (η5-C5Me5)Ru(μ2-i-PrN=C(Me)Ni-Pr)Ru(Cl)(η5-C5Me5) (3a) with NaPF6 or other metal salts of weakly coordinating anions, which is active towards catalytic atom transfer radical cyclization of N-allyl trichloroacetamides and related reactions.

Discussion

No takes yet. Share an insight, caveat, or question.

Cite This Study

Motoyama et al. (2004) studied this question.

synapsesocial.com/papers/6aa4e2508cfe0c48ab283e1b https://doi.org/10.1246/cl.2004.442

View at Publisher

Ask AI

Bookmark

Share

Keep reading

Synapse has enriched 10 related papers. Consider them for comparative context:

1Transition Metal-Promoted Free-Radical Reactions in Organic Synthesis: The Formation of Carbon-Carbon BondsOriginal Research · 1994 · 709 citations
2Atom Transfer Radical PolymerizationOriginal Research · 2001 · 7,659 citations
3Metal-Catalyzed Living Radical PolymerizationOriginal Research · 2001 · 3,274 citations
4Atom transfer radical cyclisation reactions mediated by copper complexesOriginal Research · 2001 · 351 citations
5Transition metal-catalyzed radical cyclizations: a low-temperature process for the cyclization of N-protected N-allyltrichloroacetamides to trichlorinated .gamma.-lactams and application to the stereoselective preparation of .beta.,.gamma.-disubstituted .gamma.-lactamsOriginal Research · 1993 · 135 citations
6Oxidative Addition of Allylic Substrates to Coordinatively Unsaturated Ruthenium Compounds, [Ru(η5-C5Me5)(η-amidinate)]: Preparation, Structure Elucidation, and Catalysis of Novel Ruthenium (IV)-η3-Allyl ComplexesOriginal Research · 2001 · 42 citations
7Conserved Met16 of Pseudoazurin Facilitates the Interprotein Electron Transfer to Copper-Containing Nitrite ReductaseChemistry Letters · 2026
8Synthetic Studies on Leptolyngbyalides A–C: Stereoselective Synthesis of the C16–C27 FragmentChemistry Letters · 2026
9A Highly Emissive Diarylethene Photoswitch with Efficient Reversible Switching in Solution and the Solid StateChemistry Letters · 2026
10Photoinduced molecular reorientation in liquid crystalline polymer film via an axis-selective photoreaction of benzaldehyde moieties in its side chainChemistry Letters · 2026

More from Chemistry Letters

More from Kyushu University