The outer complex initially formed on electrophilic addition has been shown to have the structure 1 in the prototypical reaction of ethene with BrCl. The rotational spectra of two isotopomers of a weakly bound complex were observed by Fourier transform microwave spectroscopy with a fast-mixing nozzle. This result is important for the understanding of the mechanism of electrophilic addition, a fundamental reaction in organic chemistry.
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Bloemink et al. (1994) studied this question.
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