Co-condensation of thermally generated silicon atoms with formaldehyde in an argon matrix and subsequent irradiation is used as an access to compounds of the composition CH 2 OSi. Isolation and matrix-spectroscopic identification of siloxiranylidene ( 2 ) and the H 2 Si·CO complex 1 are described. The comparison of the experimental and calculated IR spectra shows that 1 has a pyramidal and not a planar ketene-like structure.
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Maier et al. (1999) studied this question.
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